, , ,

<<


 >>  ()
Pages:     | 1 |   ...   | 3 | 4 ||

Ȼ . .. ...

-- [ 5 ] --

. 5. l,g,%, (l, g,T) . H3OH DEE - (2.5, 2.25, 2.26) - 1 (2.5, 3.3) (), (), - (2.5, 2.25, - 1 (2.5, 3.3) (), 2.26) (), CM (2.5, 3.4, 3.5) (), ++ (l, g,T)exp (), CM (2.5, 3.4, 3.5) () (l, g,T)exp - () . 8. l,g, %, (l,g,T)cal . 7. l,g, %, , (2.5, (l,g,T)cal - , 2.19, 2.20), , (2.23, 2.24, . 1, . 2) (2.5, 3.4,3.5). H2O , (2.5, - g, +++- l 3.4, 3.5). H2O l -, g ooo . 9. l,g, %, . 10. l,g,%, (l, (l, g,T) - , g,T) . CH4, . (2.38, 2.39), , (2.5, 3.4, 3.5). -. (2.31) (), - . (2.30) (), CH - (2.5, 3.35) - g, +++ - l (), - (2.5, 3.35) () . 11. l,g, %, . 13. , g, %, (l, g,T) . NH3 (g,T) , (2.5, 3.4, 3.5).

- (), H3OH - (), - Refprop (), - Refprop () . 12. , l, %, (g,T) , (2.5, 3.4, 3.5).

H3OH . 14. fs, . 15. fd, . SF . SF - (2.35), - +++ - [24], (2.35, . 6), +++ - (3.4),--- (3.5), --- - yd as ys as . 16. fs, %, . 17. fs, %, .

(fs, ) - . 2 CH4, . - (fs,T) - (3.4) - (2.22, . 2, ++ - (2.35, . 2) . 2), (3.4), - (fs,T) - +++ - 0 (3.2), 0 (3.2), - (2.35, - (2.19), . 1) (3.4), - . (fs,T) (3.4) (2.35, . 1), - .

(fs,T) - (2.35, . 2), - (fs,T) - . (2.30, 2.31) . 18. fs,%, (fs, ) . 19. fd, % (fd, ) - . SF6 . 2 - 0 (3.2), - - (2.23), (3.30, 3.31, 2.4), (3.4) +++ - 0 (3.2), - (2.20), (3.5) . 20. fd,%, (fd, . 21. fd dim, %, (fd ) - . CH4, . 2 dim, ) - . 2 - (3.5), - 0 - (2.23, .2, . 2), +++ - 0 (3.2), - (3.2), . (2.35, . (2.20), (3.5) 1), - . (2.35, . 2), - (2.30, 2.31) .

22. fd dim,%, (fd . 23. fd dim,%, , dim,)- . CH4, , . 2 (3.5). SF - (3.5), - 0 (3.2), - , +++ - - . (2.35, (2.35), . 1), (3.30, 3.31) - (2.35, . 2), . (2.30, 2.31) . 24. fd dim,%, . 25. fd dim,% (fd dim, ) - . . DEE xxx . (fd dim, ) HFE347mcc (3.5), xxx (3.5), +++ - 0 (3.2) +++ - . (fd dim, ) - (3.2), (2.25) (3.5) . 26. (S, S1, S2, . 27. S1(S2), S, %.

Sm), %, = var. 2 2 - S1, - S, - S2, xxx - Sm, (A, - S1, - S S1min ), (, S2min ), - (C, Sc min ), (D, Sc opt) . 29. S1, S2, SC,%, . 28. S1, S2 SC = var. H2O = var. H2O - S1 min, - S2 min, - SC min, - S1, - S2, - SC, - SC opt - S1, - S2, - SC, - SC opt . 30. S1, S2, SC,%, Bs0= var, . 31. S1, S2, SC,%, Bd0= var, H2O - S1, - S2, - SC, - SC H2 O - S1, - S2, - SC, - SC opt, - SC min opt, - SC min . 32. Zl,g(z) . 33. Zl,g(z) (3.36) Zl,g as (3.37). H2O (3.36). SF +++ - Zl, , xxx Zg(z), - Zg, , , - Zl, , +++ - Zl(z), - Zg, , , --- - Zl,g as, , - Zg(z), , - Bs0, - Zl(z), , Zl as(z), , Zg as(z), , - Bs0 = 2.2234, . 34. lgZl,g(), (l, g,) =0.0020.01. H2O . 35. Zl,g(z) . 36. Zl,g(z) Zl,g as(z). H4, . 1 Zl,g as(z). H3OH - Zl as(z), - Zg as(z), --- - Bs0, --- - Zl as(z), --- - Zg as(z), --- - Bs0, - Zg(z), , - Zg(z), , - Zl(z), , - Zl(z), , - Zg exp( ), - Zg exp( ), +++ - Zl exp( ) +++ - Zl exp( ) . 37. Zl,g(z) . 38. Zl,g(z) Zl,g as(z), Zl,g as(z), . DEE (2.19, 2.20). H2O - Zg exp( ), --- - Zl as(z), --- - Zg as(z), --- - Bs0 = 1.975, +++ - Zl exp( ), - Zg(z), - Zl (z), - Zg (z) - Zl(z), --- - Zl as(z), --- - Zg as(z), --- Bs . 39. Zl,g(z) . 40. Zl,g(z) Zl,g as(z), Zl,g as(z), (2.22, 2.23). H2O . H4, . - Zg exp ( ), --- - Zl as(z), --- - Zg as(z), --- - Bs0 = 2.263349 (. 2), +++ - Zl exp( ), -Zg(z), - Zl(z) - Zg(z) (. (2.30), - Zl(z) (. (2.31), --- - Zl as(z), , --- - Zg as(z), , --- - Bs0 ( , . 2), - Zg(z), (2.35), - Zl(z), (2.35) . 41. Zl,g(z) . 42. Zl,g as(z), Zl,g(z) Zl,g as(z), (2.25, 2.26, . 3). 2H5OH . 2H5OH - Zg exp ( ), Zl exp( ), +++ - Zl exp ( ), +++ - Zg exp( ), - Zl(z), --- - Zl as(z), --- - Zg as(z), - Bs = - Zl(z), --- Zl as(z), --- - Zg as(z) 2.2992, - Zg(z) , - Bs0, - Zg(z) . 43. 1(), (3.38), . 44. 1() (3.38), . H2O - (3.4), - .

(2.23), DEE - (2.19), (3.4), - (2.33), - (2.25), -.-.- - opt ( C, . 1, . ), --- - opt = 0.348 ( C, . 1, - - - - = 0.325, . ), --- - = 0. --- - low . 45. 1(), (3.40), . 46. . H2O - fd, . H2O +++ - CM (3.5), --- - opt = 0.1324 (2.20), - Bd1 (2.20).

( , . 1, . ), - (2.24, . 2) . 47. 2(), (3.38), . 48. Bsc() Bdc(), . H2O . H2O : - , +++ - - Bsc(), (3.42), , , - Bdc(), (3.45), = 0.325, -.-.- - Bs0, , - opt = 0.34594, -.-.- - Bd0, - - - - low . 49. 2(), (3.38), . 50. 2(), (3.38), . 4, . 2 . DEE - (3.4), - - (3.4), - (2.30, 2.31), ---- - = 0.3499 (. (2.24), ---- - = 0.348 (.

1, . ), 1, . ), ---- - = 0.325 (. 3), ---- - = 0.334, ---- - = 0.324 (. 3) (2.30, 2.31) . 51. 2(), (3.44), . 52. 2(), (3.44) , 2 . CH - , - - (3.5, .2), - (2.30, 2.31), --- - opt = 0.1098 (. 2, .

) . 53. 2(), (3.44), . DEE - (3.5), - (2.26), ---- - = 0.11, ---- - y = 0.352 (. 3) . 54 s, %, . 55. Ps, %, . CH (s,T) - . H2O - (Ps, T) 1, +++ - (4.5), - (Ps, T) MP, .2, 1 (4.2), - - - - - (Ps, T) - , (s,T) - IF -97 [41] (2.49), .2, CMP, .2.

. 56. Ps, %. SF6 . 57. Ps, %. NH - (Ps, T) - - (Ps, T) - , , - 1 - 1, (Ps, T) , (2.49), , - , (2.48), .

. 58. Ps, %. HFO-1234yf . 59. Ps, %, - (s,T) CMP (s,T) (4.5), +++ , W P. CH3OH (4.16) MP.

. 60. s, %, . 61. Ps, %, . H2O (4.5). H2O - , +++ - , MP (2.45, .1), - , (4.13), - , (2.45, (2.49) . 2) . 62. Ps, %, (s,T) , P (4.5), . NH +++ - , REFPROP, . 64. Ps, %, . 63. Ps, %, . H3OH (s,T) CP. 2H5OH x W (4.16), - - (4.21), (2.49) (2.46) . 65. S1, S2, SC, % . 66. S1, S2 SC = var. H2O Bp0 = var. H2O A, S1 min, C, S2 min, - B, SC min, D, SC opt A, S1 min, B, SC min, - C, S2 min, - D, SC opt . 67. dPs/dT, -1, . 68. d2s/dT2, -2, . H2O . H2O (2.49),+++ - (2.52),+++ - P, - M (4.13) P, - M . 70. dPs/dT, -1, . 69. d2s/dT2, -2, . CH4, . . H2O MPM, - (2.49), 1 IWM (4.14), 2 CMP MP, --- MPM,, --- - CMP:

. 71. d2s/dT2, -2, . 72. d2s/dT2, -2, . CH4: . CH3 - (2.49), - - (2.49), - , CMP, - MPM - W . 73. ds/dT, -1, . 74. ds/dT, -1, . C2H5 - , (4.17), . DEE - (2.46) - CMP, +++ - (2.46), - , -.-.- - (2.46), - - - - (dPs/dT)c CMP . 76. w(1-), . 75. d2s/dT2, -2, . DEE . H2O - CMP, +++ - (2.49), - P, (2.46), - . 77. w(1-) Rie. H w ( (2.49),+++ - P, - ) . 78. fd, . H2O - (2.49, .1), - Rie ( (2.49), - CMP, MPM (4.13) P, - PM) . 79. fde(), .

H4, (2.49),+++ - P, . 80. x(), . H2O (2.49), , . 81. x(), : CH (2.49), - , - (4.13) . 82. fs, %, . H2O (2.35), - 0.

. 83. . 84. [41] , [41] , (2.38). H2O (2.39). H2O . 86. . 85. fd, r, /, . DEE . 2 (2.26), +++ ooo , +++ IF-97 [41], -- - - Ar, fd1 (2.26), xxx fd0 xxx- (2.45), (2.5, 2.23, 2.24) (2.26), - (3.5) . 87. r/() . 2 . 88. r ooo , +++ IF-97 [41], -- - - Ar, . 2 - (2.45), (2.5, 2.23, ooo , +++ IF 97 [41], -- - - Ar, - 2.24) (2.45), (2.5, 2.23, 2.24) . 89. , . 90. , r, /, . 2 r, /, .

, C25OH IF-97 [41], - , - [6], (3.33, 3.32) (4.17), - (2.45) (2.5, 2.23, - (2.46) (2.5, 2.25, 2.24) 2.26) . 91 (). d2Ps/dT2 Y2 as . 91 (). d2Ps/dT2 Y2 as . 2 . 2 - , - (2.45), (2.49, = 0.13), - (2.49, , - = 0.5), - . 92. Cv2 . 93. Cv2, (Y1,Y2) . 2 . - (2.45), (2.5, 2.23, MPM , +++ - (2.49, = 0.5) , 2.24), , - - (2.49, = 0.13) , +++ - (2.49, = 0.5) , - Y2, (2.49, = 0.5), -Y1, . 94. Cv2, Y1 Y2. DEE Cv2, ;

- Y2;

+++ - ;

- Y1;

Cv2, ;

- Y2, - Y2, . 96. |Cs |, d2Ps/dT2 . 95. |Cs | .

Cv2 . H2O:

H2O:

, IF-97 [41], , ++ - (2.45), (2.5, 2.23, 2.24), IF-97 [41], o- (2.49, = 0.5) , ++ - (2.45), (2.5, - (2.49, = 0.13) 2.23, 2.24), o- (2.49, = 0.5) , - (IAWPS-97), - Cv2, (2.49, = 0.5) ;

d2Ps/dT2, (2.49, = 0.5) (l,g,T)cal 4 [23] l, /3 g, /3 l, /3 g, / , , 90.694 451.48 0.251 147 363.82 14. 91 451.07 0.26 148 361.87 14. 92 449.73 0.292 149 359.9 15. 93 448.4 0.327 150 357.9 16. 94 447.05 0.365 151 355.88 17. 95 445.71 0.407 152 353.83 17. 96 444.35 0.452 153 351.75 18. 97 442.99 0.502 154 349.64 19. 98 441.63 0.555 155 347.51 20. 99 440.26 0.612 156 345.34 21. 100 438.89 0.675 157 343.14 22. 101 437.5 0.741 158 340.9 23. 102 436.12 0.813 159 338.63 24. 103 434.72 0.89 160 336.31 25. 104 433.32 0.973 161 333.96 26. 105 431.92 1.061 162 331.57 27. 106 430.5 1.156 163 329.13 28. 107 429.08 1.256 164 326.64 30. 108 427.65 1.363 165 324.1 31. 109 426.22 1.477 166 321.5 32. 110 424.78 1.598 167 318.85 34. 111 423.33 1.727 168 316.14 35. 112 421.87 1.863 169 313.35 37. 113 420.4 2.006 170 310.5 38. 114 418.93 2.159 171 307.57 40. 115 417.45 2.319 172 304.56 42. 116 415.96 2.489 173 301.45 44. 117 414.46 2.667 174 298.25 46. 118 412.95 2.856 175 294.94 48. 119 411.43 3.054 176 291.5 50. 120 409.9 3.262 177 287.93 53. 121 408.36 3.481 178 284.21 55. 122 406.82 3.71 179 280.32 58. 123 405.26 3.951 180 276.23 61. 124 403.69 4.203 181 271.91 64. 125 402.11 4.467 182 267.33 67. 126 400.52 4.743 183 262.43 71. 127 398.92 5.032 184 257.14 75. 128 397.3 5.335 185 251.36 80. 129 395.68 5.651 186 244.93 85. 130 394.04 5.98 187 237.61 91. 131 392.39 6.325 187.706 231.67 96. 132 390.72 6.684 188 228.93 99. 133 389.04 7.058 188.658 222.035 105. 134 387.35 7.448 189 217.87 109. 135 385.64 7.855 189.23 214.743 112. 136 383.92 8.278 189.611 208.73 117. 137 382.18 8.719 190 200.78 125. 138 380.42 9.178 190.183 195.798 129. 139 378.65 9.655 190.373 188.612 137. 140 376.87 10.152 190.469 183.053 142. 141 375.06 10.668 190.526 177.48 148. 142 373.24 11.205 190.545 174.215 151. 143 371.39 11.763 190.554 171.551 154. 144 369.53 12.343 190.562 167.152 158. 145 367.65 12.945 190.562 162.66 162. 146 365.74 13. (l,g,T)exp 4 [22] l, /3 g, /3 l, /3 g, / , , 91 451.055 0.2603 170 310.457 38. 95 445.692 0.4079 175 294.895 48. 105 431.915 1.0635 180 276.188 61. 110 424.774 1.601 182 267.276 67. 111.631 422.398 1.8141 184 257.07 75. 115 417.434 2.3223 186 244.837 85. 120 409.886 3.2633 187 237.503 91. 125 402.084 4.4702 188 228.808 99. 130 394.007 5.9842 189 217.71 109. 135 385.598 7.8613 189.5 210.407 116. 140 376.833 10.159 189.8 204.94 121. 145 367.618 12.9547 190 200.473 125. 150 357.872 16.3371 190.1 197.85 127. 155 347.49 20.4284 190.2 194.82 130. 160 336.296 25.3952 190.3 191.2 134. 160 336.287 25.3948 190.4 186.46 138. 165 324.069 31.4689 190.45 183.28 142. (l,g,Ps,T)exp SF6 [24] l, /3 g, / , s, 224.000 0.235814 1842.835 19. 225.000 0.245899 1837.909 20. 227.000 0.267051 1827.981 22. 230.000 0.301338 1812.898 25. 235.000 0.365769 1787.214 30. 240.000 0.440074 1760.782 36. 245.000 0.525162 1733.512 43. 250.000 0.621971 1705.298 50. 255.000 0.731471 1676.016 59. 260.000 0.854655 1645.524 70. 265.000 0.992552 1613.634 81. 270.000 1.14624 1580.130 95. 275.000 1.31684 1544.712 110. 280.000 1.50553 1507.011 128. 285.000 1.71355 1466.510 149. 290.000 1.94229 1422.491 173. 295.000 2.19324 1373.888 202. 300.000 2.46811 1318.987 238. 305.000 2.76896 1254.764 283. 308.000 2.96296 1209.334 317. 310.000 3.09834 1174.686 344. 311.000 3.16795 1155.562 359. 313.000 3.31114 1112.288 394. 314.600 3.42979 1070.411 430. 316.000 3.536786 1024.540 470. 316.800 3.599380 991.302 500. 317.500 3.655111 954.062 535. 318.000 3.695511 917.807 569. 318.35 3.724099 880.474 605. 318.55 3.740558 846.391095 638. 318.650 3.748816 816.080 668. (g,T) NH , g, /3 - , g, /3 - 1 222.289 0.

371581 [25] 43 280,619 4,47487 [25] 2 223,159 0,390442 [25] 44 280,699 4,48209 [25] 3 223,299 0,393468 [25] 45 282,988 4,82323 [25] 4 226,738 0,472634 [25] 46 283,518 4,91232 [25] 5 227,748 0,495145 [25] 47 288,147 5,70679 [25] 6 231,088 0,585035 [25] 48 288,706 5,83397 [25] 7 232,668 0,636578 [25] 49 288,756 5,82276 [25] 8 234,238 0,682501 [25] 50 292,755 6,60153 [25] 9 234,238 0,687569 [25] 51 292,815 6,62734 [25] 10 234,388 0,692905 [25] 52 293,075 6,66667 [25] 11 235,027 0,711541 [25] 53 293,515 6,77002 [25] 12 235,927 0,745935 [25] 54 293,675 6,80041 [25] 13 237,587 0,803859 [25] 55 295,445 7,17463 [25] 14 239,867 0,896781 [25] 56 296,675 7,45657 [25] 15 240,167 0,905551 [25] 57 297,195 7,57576 [25] 16 241,137 0,945358 [25] 58 298,084 7,7682 [25] 17 252,624 1,56421 [25] 59 298,214 7,80701 [25] 18 253,334 1,60927 [25] 60 299,774 8,17528 [25] 19 260,483 2,16104 [25] 61 305,172 9,5813 [25] 20 260,613 2,17316 [25] 62 319,458 14,2653 [25] 21 262,602 2,33242 [25] 63 323,667 15,9872 [25] 22 262,712 2,33918 [25] 64 326 16,942 [29] 23 263,452 2,42289 [25] 65 330 18,812 [29] 24 263,482 2,41249 [25] 66 334 20,862 [29] 25 269,101 2,99383 [25] 67 338 23,109 [29] 26 270,061 3,10183 [25] 68 342 25,574 [29] 27 271,9 3,2924 [25] 69 346 28,277 [29] 28 272,49 3,36202 [25] 70 350 31,244 [29] 29 272,82 3,40588 [25] 71 354 34,502 [29] 30 273,4 3,47283 [25] 72 358 38,089 [29] 31 273,44 3,4785 [25] 73 362 42,049 [29] 32 273,57 3,49479 [25] 74 366 46,443 [29] 33 273,99 3,56544 [25] 75 370 51,35 [29] 34 275 3,69809 [25] 76 374 56,881 [29] 35 275,09 3,70014 [25] 77 378 63,191 [29] 36 275,57 3,76067 [25] 78 382 70,497 [29] 37 275,91 3,80546 [25] 79 386 79,111 [29] 38 276,13 3,84438 [25] 80 390 89,494 [29] 39 278,559 4,15835 [25] 81 394 102,36 [29] 40 278,649 4,1691 [25] 82 398 119,1 [29] 41 278,829 4,21461 [25] 83 402 144,02 [29] 42 278,939 4,23012 [25] 84 404 166,24 [29] (l,g,T) NH , l, /3 - g, /3* , l, /3 - g, /3* 1 222,669 702,627 [46] 0,380111 54 293,375 609,979 [46] 6, 2 223,199 702,099 [46] 0,3910178 55 294,145 608,776 [46] 6, 3 223,479 701,863 [46] 0,3968855 56 298,144 602,8 [46] 7, 4 226,728 697,807 [46] 0,4705698 57 303,013 595,507 [46] 9, 5 227,138 697,326 [46] 0,4806339 58 303,123 595,295 [46] 9, 6 227,238 697,253 [46] 0,4831156 59 303,243 595,05 [46] 9, 7 227,248 697,131 [46] 0,4833644 60 303,303 595,086 [46] 9, 8 227,578 696,816 [46] 0,491634 61 310 585,1 [44] 10, 9 227,283 696,903 [46] 0,4842359 62 312,41 580,498 [46] 11, 10 228,038 696,325 [46] 0,5033584 63 312,411 580,619 [46] 11, 11 228,278 696,069 [46] 0,5095677 64 312,69 580,151 [46] 11, 12 228,538 695,599 [46] 0,5163663 65 312,7 580,211 [46] 11, 13 233,018 690,255 [46] 0,6459287 66 313,08 579,606 [46] 11, 14 233,458 689,646 [46] 0,6599898 67 313,35 579,13 [46] 12, 15 233,568 689,603 [46] 0,6635443 68 317,149 572,951 [46] 13, 16 242,167 679,062 [46] 0,9947413 69 317,209 572,885 [46] 13, 17 242,267 679,048 [46] 0,9992667 70 318,059 571,291 [46] 13, 18 242,277 679,002 [46] 0,9997202 71 318,109 571,363 [46] 13, 19 242,497 678,767 [46] 1,0097389 72 318,129 571,36 [46] 13, 20 243,116 677,782 [46] 1,0383681 73 318,229 571,177 [46] 13, 21 243,246 677,626 [46] 1,0444639 74 318,269 571,115 [46] 13, 22 243,286 677,571 [46] 1,0463454 75 318,269 571,115 [46] 13, 23 257,933 658,887 [46] 1,9464828 76 318,418 570,854 [46] 13, 24 258,213 658,592 [46] 1,9683307 77 319,158 569,46 [46] 14, 25 258,323 658,402 [46] 1,9769673 78 319,358 569,168 [46] 14, 26 258,353 658,363 [46] 1,9793279 79 320 568,49 [45] 14, 27 258,354 658,402 [46] 1,9794067 80 320,778 566,768 [46] 14, 28 265,312 649,123 [46] 2,5911104 81 322,937 563,231 [46] 15, 29 265,522 648,879 [46] 2,6116674 82 322,938 563,231 [46] 15, 30 265,522 648,828 [46] 2,6116674 83 322,977 563,171 [46] 15, 31 265,582 648,845 [46] 2,6175646 84 323,037 563,054 [46] 15, 32 265,582 648,782 [46] 2,6175646 85 323,077 562,905 [46] 15, 33 265,732 648,781 [46] 2,6323538 86 323,307 562,613 [46] 15, 34 268,971 644,234 [46] 2,968249 87 330 550,99 [45] 18, 35 272,59 639,296 [46] 3,3828679 88 333,354 544,802 [46] 20, 36 272,62 639,296 [46] 3,3864868 89 336,354 539,307 [46] 22, 37 272,65 639,333 [46] 3,3901088 90 340 532,29 [45] 24, 38 273,1 638,614 [46] 3,4448077 91 340 532,29 [45] 24, 39 273,12 638,655 [46] 3,4472549 92 350 511,76 [45] 31, 40 273,15 638,651 [46] 3,4509283 93 350 511,9 [45] 31, 41 273,2 638,46 [46] 3,4570575 94 353,709 504,322 [46] 34, 42 273,2 638,5 [46] 3,4570575 95 360 489,68 [45] 39, 43 280,399 628,563 [46] 4,4340464 96 360 489,7 [45] 39, 44 280,429 628,528 [46] 4,4385302 97 364,366 479,773 [46] 44, 45 283,148 624,637 [46] 4,8600919 98 369,395 466,895 [46] 50, 46 283,149 624,586 [46] 4,8602526 99 370 464,89 [45] 51, 47 283,698 623,9 [46] 4,9490974 100 370 464,9 [45] 51, 48 285,967 620,759 [46] 5,3300535 101 373,174 456,681 [46] 55, 49 286,017 620,717 [46] 5,3387026 102 380 435,95 [45] 66, 50 288,147 617,5 [44] 5,7176392 103 380 435,84 [45] 66, 51 293,155 610,273 [46] 6,6931993 104 390 399,52 [45] 89, 52 293,175 610,255 [46] 6,6973446 105 390 399,33 [45] 89, 53 293,325 610,065 [46] 6,7285 106 400 343,53 [45] 129, *- (2.53) (l,g,T) () [11;

21] l, /3 g, / , 253.15 824,417 0, 263.15 815.657 0. 273.15 807.016 0. 283.15 798.439 0. 293.15 789.87 0. 303.15 781.252 0. 313.15 772.526 0. 323.15 763.632 0. 333.15 754.508 0. 351.05 736.78 1. 373.15 713.14 3. 373.15 712.93 3. 423.15 648.27 14. 423.15 647.87 15. 423.85 647.30 15. 473.15 554.66 49. 473.15 555.23 50. 493.15 495.58 80. 493.15 496.07 80. 498.15 476.56 91. 498.15 476.24 91. 503.15 453.07 104. 503.15 452.12 105. 508.15 420.33 124. 508.15 420.15 124. 511.15 392.86 154. 511.15 392.57 154. 513.15 361.08 179. 513.15 362.84 179. (s,T)cal 4 [22] , K , , K , , K , 90.694 0.011696 129 0.34575 168 2. 91 0.012164 130 0.36732 169 2. 92 0.013801 131 0.38986 170 2. 93 0.015613 132 0.41341 171 2. 94 0.017613 133 0.43799 172 2. 95 0.019815 134 0.46363 173 2. 96 0.022233 135 0.49035 174 2. 97 0.024882 136 0.51819 175 2. 98 0.027778 137 0.54716 176 2. 99 0.030937 138 0.5773 177 2. 100 0.034376 139 0.60863 178 3. 101 0.038111 140 0.64118 179 3. 102 0.04216 141 0.67498 180 3. 103 0.046542 142 0.71006 181 3. 104 0.051275 143 0.74644 182 3. 105 0.056377 144 0.78415 183 3. 106 0.061868 145 0.82322 184 3. 107 0.067769 146 0.86368 185 3. 108 0.074099 147 0.90555 186 3. 109 0.080879 148 0.94887 187 4. 110 0.08813 149 0.99367 188 4. 111 0.095874 150 1.04 189 4. 112 0.10413 151 1.0878 190 4. 113 0.11293 152 1.1372 190.1 4. 114 0.12228 153 1.1882 190.2 4. 115 0.13221 154 1.2408 190.3 4. 116 0.14275 155 1.295 190.4 4. 117 0.15392 156 1.3509 190.42 4. 118 0.16574 157 1.4086 190.44 4. 119 0.17824 158 1.468 190.46 4. 120 0.19143 159 1.5291 190.48 4. 121 0.20535 160 1.5921 190.5 4. 122 0.22002 161 1.6569 190.51 4. 123 0.23546 162 1.7235 190.52 4. 124 0.2517 163 1.7921 190.53 4. 125 0.26876 164 1.8626 190.54 4. 126 0.28667 165 1.9351 190.55 4. 127 0.30546 166 2. 128 0.32514 167 2. (s,T)exp 4 [22] , K s, , K s, , K s, 91 0.01217 155 1.295683 188 4. 95 0.019822 160 1.592857 188 4. 100 0.03441 160 1.59299 189 4. 103 0.046582 160 1.592945 189 4. 105 0.056416 160 1.592951 189.5 4. 110 0.088221 165 1.936203 189.8 4. 111.631 0.101105 170 2.329617 190 4. 115 0.132337 175 2.777972 190.1 4. 116 0.142853 180 3.286813 190.2 4. 120 0.191568 180 3.286673 190.3 4. 125 0.268981 182 3.508767 190.4 4. 130 0.367612 184 3.742227 190.45 4. 135 0.490707 186 3.987867 190.5 4. 140 0.64163 186 3.987752 190.53 4. 145 0.823757 187 4. 150 1.04058 187 4. (s,T)exp (), [11;

21] , K s, , K s, 1 253.15 0.0003494 20 423.15 0. 2 263.15 0.0007708 21 473.15 2. 3 273.15 0.0015993 22 493.15 4. 4 283.15 0.0031395 23 493.15 4. 5 293.15 0.0058614 24 498.15 4. 6 303.15 0.0104554 25 498.15 4. 7 313.15 0.0178924 26 498.15 4. 8 323.15 0.0294826 27 503.15 5. 9 333.15 0.0469311 28 503.15 5. 10 343.15 0.0723834 29 503.15 5. 11 353.15 0.1084591 30 508.15 5. 12 363.15 0.1582694 31 508.15 5. 13 373.15 0.2253 32 511.15 5. 14 373.15 0.2251 33 511.15 5. 15 398.15 0.498 34 512.15 5. 16 398.15 0.4973 35 512.15 5. 17 398.15 0.4969 36 513.15 6. 18 423.15 0.983 37 513.15 6. 19 423.15 0. (s,T)exp () - - , K , , K , , K , 1 195,48 6,07 [47] 52 258,128 236,101 [48] 103 313,068 1551,42 [48] 2 203,15 10,92 [47] 53 258,133 236,101 [48] 104 313,135 1554,74 [48] 3 208,15 15,603 [47] 54 258,15 236,314 [48] 105 313,15 1555,5 [47] 4 213,15 21,873 [47] 55 258,15 236,25 [47] 106 318,058 1777,55 [48] 5 218,15 30,127 [47] 56 258,151 236,327 [47] 107 318,104 1779,68 [48] 6 223,15 40,821 [47] 57 263,128 290,629 [48] 108 318,15 1782,6 [47] 7 228,15 54,479 [47] 58 263,132 290,616 [48] 109 318,21 1785,04 [48] 8 233,15 71,689 [47] 59 263,142 290,829 [48] 110 323,15 2033,7 [47] 9 238,15 93,104 [47] 60 263,143 290,736 [48] 111 323,173 2034,81 [48] 10 239,038 97,472 [48] 61 263,15 290,83 [47] 112 323,22 2036,38 [48] 11 239,411 99,3385 [48] 62 263,153 290,709 [48] 113 323,254 2038,9 [48] 12 239,768 101,152 [48] 63 268,09 353,851 [48] 114 328,14 2310,08 [48] 13 239,789 101,232 [48] 64 268,13 354,611 [48] 115 328,15 2310,6 [47] 14 239,794 101,338 [48] 65 268,135 354,598 [48] 116 333,15 2614,7 [47] 15 239,795 101,325 [48] 66 268,137 354,664 [48] 117 333,191 2617,4 [48] 16 239,796 101,338 [48] 67 268,141 354,677 [48] 118 333,194 2617,44 [48] 17 239,803 101,338 [48] 68 268,146 354,864 [48] 119 333,196 2617,86 [48] 18 239,843 101,538 [48] 69 268,15 354,91 [47] 120 333,2 2618,2 [48] 19 239,852 101,485 [48] 70 273,147 429,391 [48] 121 338,15 2947,8 [47] 20 239,86 101,498 [48] 71 273,15 429,365 [48] 122 338,184 2951,32 [48] 21 239,874 101,618 [48] 72 273,15 429,391 [48] 123 338,192 2951,7 [48] 22 239,887 101,778 [48] 73 273,15 429,351 [48] 124 338,196 2951,77 [48] 23 239,9 101,778 [48] 74 273,15 429,405 [48] 125 343,143 3312,19 [48] 24 239,907 101,818 [48] 75 273,15 429,57 [47] 126 343,15 3311,7 [47] 25 239,913 101,805 [48] 76 278,123 515,198 [48] 127 343,232 3323,06 [49] 26 239,914 101,898 [48] 77 278,15 515,97 [47] 128 348,181 3718,09 [49] 27 239,916 101,925 [48] 78 278,171 516,158 [48] 129 348,196 3717,03 [49] 28 240,034 102,512 [48] 79 283,142 614,736 [48] 130 348,327 3730,36 [49] 29 242,705 116,977 [48] 80 283,15 615,31 [47] 131 348,48 3745,03 [49] 30 243,075 119,097 [48] 81 283,169 615,336 [48] 132 353,269 4153,66 [49] 31 243,118 119,43 [48] 82 283,183 615,723 [48] 133 358,337 4634,55 [49] 32 243,145 119,604 [48] 83 288,15 728,81 [47] 134 358,387 4642,95 [49] 33 243,15 119,45 [47] 84 288,155 728,38 [48] 135 358,492 4657,35 [49] 34 243,152 119,577 [48] 85 288,267 731,34 [48] 136 363,126 5125,04 [49] 35 243,243 120,083 [48] 86 288,306 732,113 [48] 137 363,586 5174,11 [49] 36 248,096 151,214 [48] 87 293,144 856,916 [48] 138 368,585 5717,8 [49] 37 248,105 151,281 [48] 88 293,15 857,77 [47] 139 368,725 5737,53 [49] 38 248,12 151,454 [48] 89 293,163 857,596 [48] 140 368,776 5747,93 [49] 39 248,136 151,534 [48] 90 293,165 857,556 [48] 141 373,43 6299,88 [49] 40 248,137 151,494 [48] 91 298,125 1001,93 [48] 142 373,634 6330,55 [49] 41 248,15 151,588 [48] 92 298,15 1003,5 [47] 143 378,093 6897,97 [49] 42 248,15 151,51 [47] 93 298,16 1003,26 [48] 144 378,193 6898,5 [49] 43 250,343 167,626 [48] 94 298,225 1005,04 [48] 145 382,992 7561,78 [49] 44 250,373 167,88 [48] 95 298,32 1008,17 [48] 146 388,13 8321,45 [49] 45 253,142 190,158 [48] 96 303,079 1164,69 [48] 147 388,131 8309,72 [49] 46 253,146 190,238 [48] 97 303,145 1166,54 [48] 148 393,037 9088,99 [49] 47 253,149 190,198 [48] 98 303,15 1167,5 [47] 149 398,119 9957,31 [49] 48 253,15 190,144 [48] 99 308,15 1351 [47] 150 403,118 10902,6 [50] 49 253,15 190,14 [47] 100 308,164 1351 [48] 151 404,118 11105,2 [50] 50 253,152 190,291 [48] 101 308,2 1351,49 [48] 152 405,118 11297,7 [50] 51 258,107 235,954 [48] 102 313,068 1551,58 [48] (l,g,s,ds/dT,d2s/dT2T)mid l, g, s, ds/dT,d2s/dT2, 2,2, (2.5, 3.4, 3.5) (4.5). H2O d2Ps/dT2, l mid, g mid, l, g, T, K Ps, dPs/dT, /3 /3 /3 /3 Ma/K Ma Ma/K 640.15 0.011 479.889 178.775 480.587 178.579 20.308 0,2429 0, 645.15 3.137e-3 421.109 226.886 422.579 226.486 21.556 0,2573 0, 646.15 1.592e-3 399.218 246.312 400.797 245.94 21.814 0,2604 0, 646.35 1.282e-3 393.368 251.644 394.948 251.293 21.866 0,2611 0, 646.55 9.735e-4 386.561 257.921 388.126 257.603 21.918 0,2617 0, 646.75 6.644e-4 378.229 265.716 379.746 265.447 21.970 0,2624 0, 646.85 5.099e-4 373.116 270.561 374.586 270.328 21.996 0,2628 0, 646.95 3.554e-4 366.905 276.511 368.


299 276.323 22.023 0,2631 0, 647.00 2.781e-4 363.135 280.156 364.472 279.998 22.036 0,2633 0, 647.05 2.009e-4 358.627 284.551 359.884 284.428 22.049 0,2634 0, 647.1 1.236e-4 352.821 290.268 353.955 290.192 22.062 0,2636 0, 647.11 1.082e-4 351.395 291.682 352.496 291.617 22.065 0,2637 0, 647.12 9.271e-5 349.833 293.236 350.894 293.183 22.067 0,26374 0, 647.13 7.726e-5 348.093 294.973 349.109 294.932 22.070 0,26377 0, 647.14 6.181e-5 346.114 296.956 347.075 296.929 22.072 0,26381 0, 647.15 4.635e-5 343.784 299.301 344.677 299.288 22.075 0,26385 0, 647.16 3.09e-5 340.882 302.238 341.684 302.242 22.078 0,26388 0, 647.17 1.545e-5 336.794 306.406 337.454 306.428 22.080 0,26392 0, 647.18 0 321.915 321.915 321.915 321.915 22.083 0, 2. l, g, fs, fd, s, ds/dT,d2s/dT2, 2,2, (2.5, 3.4, 3.5), (4.5). SF g,/3 l,/3 d2Ps/dT2, T, K fs fd Ps, Ma dPs/dT, Ma/K a/K 223.555 0.299 19.501 1.845e3 0.256 1.230 0.231422 0.00979 0. 225 0.294 20.682 1.838e3 0.252 1.224 0.245899 0.01025 0. 227 0.288 22.40 1.828e3 0.246 1.216 0.267057 0.010912 0. 230 0.278 25.167 1.813e3 0.238 1.204 0.301343 0.011957 0. 235 0.263 30.332 1.787e3 0.224 1.183 0.365764 0.013842 0. 240 0.247 36.269 1.761e3 0.21 1.162 0.440063 0.015909 0. 245 0.231 43.082 1.733e3 0.197 1.139 0.525157 0.01816 0. 250 0.216 50.891 1.705e3 0.183 1.114 0.621981 0.020601 0. 255 0.2 59.834 1.676e3 0.169 1.089 0.731489 0.023235 0. 260 0.184 70.072 1.646e3 0.156 1.061 0.854671 0.026071 0. 265 0.169 81.8 1.614e3 0.142 1.032 0.992554 0.029118 0. 270 0.153 95.256 1.58e3 0.129 1 1.146217 0.032385 0. 275 0.137 110.737 1.545e3 0.115 0.966 1.316796 0.035886 0. 280 0.121 128.627 1.507e3 0.102 0.929 1.505489 0.039633 0. 285 0.106 149.439 1.467e3 0.089 0.887 1.71356 0.04364 0. 290 0.09 173.886 1.422e3 0.075 0.841 1.942359 0.047928 0. 295 0.074 203.025 1.374e3 0.062 0.789 2.19335 0.052524 0. 300 0.059 238.537 1.319e3 0.049 0.728 2.46819 0.057478 0. 305 0.043 283.425 1.255e3 0.036 0.654 2.768887 0.062888 0. 308 0.034 317.234 1.209e3 0.028 0.601 2.962792 0.066425 0. 310 0.027 344.12 1.175e3 0.023 0.559 3.098139 0.068946 0. 311 0.024 359.352 1.156e3 0.021 0.536 3.167741 0.070267 0. 313 0.018 394.836 1.112e3 0.015 0.483 3.311029 0.073057 0. 314 0.015 416.08 1.087e3 0.013 0.452 3.384823 0.074542 0. 315 0.012 440.818 1.059e3 0.01 0.416 3.460138 0.076103 0. 316 8.5e-3 470.788 1.025e3 7.544e-3 0.373 3.53706 0.077757 0. 317 5.362e-3 509.763 982.017 4.897e-3 0.318 3.615693 0.079532 0. 318 2.225e-3 569.889 917.84 2.168e-3 0.234 3.696181 0.081482 0. 318.5 6.558e-4 628.949 856.618 7.117e-4 0.153 3.73719 0.082573 0. 318.6 3.42e-4 651.748 833.348 3.952e-4 0.122 3.745459 0.08281 0. 318.62 2.793e-4 657.872 827.127 3.292e-4 0.114 3.747115 0.082859 0. 318.64 2.165e-4 664.982 819.916 2.618e-4 0.104 3.748773 0.082909 0. 318.66 1.537e-4 673.614 811.182 1.925e-4 0.093 3.750432 0.082959 0. 318.68 9.099e-5 685.017 799.672 1.202e-4 0.077 3.752092 0.083011 0. 318.7 2.824e-5 704.105 780.468 4.221e-5 0.051 3.753752 0.083065 0. 318.702 2.196e-5 707.291 777.27 3.372e-5 0.047 3.753918 0.083071 0. 318.704 1.569e-5 711.144 773.403 2.497e-5 0.042 3.754085 0.083076 0. E . , (2.5, 3.4, 3.5) (4.5) l, /3 g, / , s, r, / 366 475,271 46,4342 5,43195408 783, 367 472,74 47,6195 5,54300231 775, 368 470,174 48,8391 5,6557342 766, 369 467,573 50,0945 5,77016806 758, 370 464,933 51,3873 5,88632269 749, 371 462,254 52,7193 6,00421735 740, 372 459,534 54,0923 6,12387185 731, 373 456,77 55,5085 6,24530659 722, 374 453,961 56,97 6,36854265 712, 375 451,105 58,4792 6,49360179 703, 376 448,198 60,0386 6,62050659 693, 377 445,238 61,6513 6,74928047 683, 378 442,223 63,3201 6,87994783 673, 379 439,148 65,0485 7,01253411 662, 380 436,01 66,8403 7,1470659 652, 381 432,806 68,6995 7,28357108 641, 382 429,53 70,6307 7,42207891 630, 383 426,178 72,639 7,5626202 619, 384 422,745 74,7299 7,70522749 607, 385 419,223 76,9099 7,84993517 595, 386 415,607 79,1861 7,99677975 583, 387 411,888 81,5666 8,14580003 571, 388 408,056 84,0607 8,29703739 558, 389 404,102 86,679 8,45053607 545, 390 400,013 89,434 8,60634352 531, 391 395,774 92,34 8,76451077 517, 392 391,369 95,4143 8,92509288 502, 393 386,776 98,6773 9,08814948 487, 394 381,971 102,154 9,25374539 471, 395 376,923 105,874 9,42195137 454, 396 371,593 109,877 9,59284506 437, 397 365,93 114,211 9,76651207 418, 398 359,868 118,942 9,9430475 398, 399 353,315 124,156 10,1225578 377, 400 346,141 129,98 10,30516333 353, 400,5 342,263 133,175 10,39766909 341, 401 338,148 136,601 10,49100203 328, 401,5 333,751 140,299 10,58518301 313, 402 329,013 144,326 10,68023488 298, 402,5 323,85 148,761 10,77618282 282, 403 318,139 153,719 10,87305497 263, 403,5 311,689 159,379 10,97088324 243, 404 304,174 166,049 11,06970469 219, 404,1 302,495 167,548 11,08959192 214, 404,2 300,743 169,118 11,10952102 208, 404,3 298,908 170,765 11,12949243 202, 404,4 296,978 172,501 11,14950659 196, 404,5 294,94 174,34 11,16956397 190, 404,6 292,777 176,296 11,18966509 183, 404,7 290,465 178,392 11,20981048 176, 404,8 287,975 180,656 11,23000075 168, 404,9 285,267 183,126 11,25023652 160, 405 282,282 185,857 11,27051851 151, 405,1 278,932 188,932 11,29084753 140, 405,2 275,073 192,489 11,3112245 128, 405,3 270,444 196,778 11,33165052 114, 405,4 264,453 202,367 11,352127 96, 405,5 255,052 211,249 11,37265593 , (2.

5, 3.4, 3.5) (4.5). H3OH g, /3 l, / , s, ds/dT, / r, / -7 -8 - 175.61 1.87*10 3.07*10 4.12*10 904.20 1310. 3.76*10-7 5.84*10-8 8.06*10- 180 899.43 1304. 8.01*10-7 1.2*10-7 1.66*10- 185 894.08 1302. 1.64*10-6 2.3*10-7 3.30*10- 190 888.81 1296. 3.22*10-6 4.2*10-7 6.31*10- 195 883.63 1294. 6.10*10-6 7.5*10- 200 0.000117 878.52 1286. 1.12*10-5 1.31*10- 205 0.000209 873.48 1286. 1.98*10-5 2.22*10- 210 0.000363 868.50 1283. 3.43*10-5 3.65*10- 215 0.000612 863.59 1281. 5.76*10-5 5.85*10- 220 0.001006 858.74 1274. 9.44*10-5 9.15*10- 225 0.001613 853.94 1278. 1.4*10- 230 0.000151 0.002529 849.19 1271. 2.09*10- 235 0.000237 0.003879 844.49 1268. 3.07*10- 240 0.000363 0.005832 839.82 1264. 4.42*10- 245 0.000547 0.008605 835.20 1260. 6.26*10- 250 0.00081 0.0125 830.61 1251. 8.71*10- 255 0.001178 0.0178 826.04 1247. 260 0.001687 0.000119 0.025 821.50 1241. 265 0.002381 0.000161 0.0346 816.97 1235. 270 0.003312 0.000215 0.0472 812.46 1230. 275 0.004548 0.000283 0.0636 807.95 1224. 280 0.006169 0.000368 0.0848 803.45 1216. 285 0.008268 0.000474 0.1117 798.95 1209. 290 0.01096 0.000604 0.1457 794.44 1201. 295 0.014375 0.000761 0.1881 789.92 1193. 300 0.018667 0.000951 0.2406 785.38 1185. 305 0.024011 0.001179 0.3051 780.82 1177. 310 0.030608 0.001448 0.3837 776.23 1169. 315 0.038684 0.001766 0.4789 771.61 1160. 320 0.048493 0.002137 0.5933 766.95 1151. 325 0.06032 0.002569 0.7299 762.23 1142. 330 0.074479 0.003067 0.8921 757.47 1133. 335 0.091316 0.003639 1.0837 752.65 1123. 340 0.111209 0.004292 1.3086 747.76 1113. 345 0.13457 0.005033 1.5715 742.79 1102. 350 0.16185 0.005869 1.8770 737.74 1091. 355 0.19352 0.006808 2.2308 732.61 1080. 360 0.23011 0.007858 2.6384 727.38 1068. 365 0.27217 0.009024 3.1063 722.04 1055. 370 0.32028 0.01031 3.6414 716.59 1042. 375 0.37508 0.01173 4.2509 711.01 1029. 380 0.43722 0.01329 4.9430 705.29 1015. 385 0.50741 0.015 5.7264 699.44 1000. 390 0.58637 0.01685 6.6105 693.42 984. 395 0.67490 0.01886 7.6056 687.23 968. 400 0.77379 0.02102 8.7228 680.86 951. 405 0.88390 0.02335 9.9746 674.29 934. 410 1.0061 0.02585 11.375 667.50 916. 415 1.1413 0.02853 12.938 660.48 897. 420 1.2906 0.03138 14.681 653.21 877. 425 1.4548 0.03442 16.623 645.66 857. 430 1.6350 0.03766 18.787 637.81 836. 435 1.8323 0.04109 21.197 629.62 814. 440 2.0478 0.04473 23.884 621.07 792. 445 2.2827 0.04860 26.882 612.12 769. 450 2.5382 0.05271 30.236 602.71 745. 452 2.6464 0.05442 31.688 598.81 735. 454 2.7583 0.05618 33.209 594.82 725. 456 2.8737 0.05798 34.803 590.75 714. 458 2.9929 0.05983 36.476 586.58 704. 460 3.1160 0.06172 38.231 582.31 693. 462 3.2429 0.06367 40.076 577.93 683. 464 3.3739 0.06566 42.016 573.44 672. 466 3.5089 0.06772 44.058 568.84 660. 468 3.6482 0.06983 46.211 564.10 649. 470 3.7917 0.07200 48.483 559.23 637. 472 3.9397 0.07423 50.885 554.22 625. 474 4.0921 0.07653 53.428 549.04 612. 476 4.2491 0.07890 56.126 543.70 600. 478 4.4109 0.08135 58.994 538.17 586. 480 4.5774 0.08387 62.051 532.45 573. 482 4.7489 0.08647 65.362 526.50 558. 484 4.9254 0.08916 68.906 520.31 543. 486 5.1071 0.09195 72.710 513.85 527. 488 5.2941 0.09483 76.807 507.08 511. 490 5.4865 0.09782 81.239 499.97 494. 492 5.6845 0.1009 86.054 492.47 476. 494 5.8883 0.1041 91.316 484.52 457. 496 6.0979 0.1074 97.107 476.03 436. 498 6.3136 0.1109 103.54 466.90 415. 500 6.5355 0.1145 110.75 456.97 391. 501 6.6489 0.1164 114.71 451.65 379. 502 6.7639 0.1183 118.96 446.05 366. 503 6.8806 0.1202 123.54 440.11 352. 504 6.9989 0.1222 128.50 433.79 337. 505 7.1190 0.1242 133.92 427.01 321. 506 7.2409 0.1263 139.91 419.67 304. 507 7.3645 0.1284 146.60 411.62 286. 508 7.4900 0.1306 154.21 402.64 265. 509 7.6173 0.1328 163.09 392.40 242. 510 7.7466 0.1351 173.85 380.27 215. 511 7.8778 0.1375 187.81 364.94 181. 512 8.0110 0.1399 209.03 342.32 133. 512.1 8.0245 0.1401 212.04 339.16 126. 512.2 8.0379 0.1403 215.37 335.69 119. 512.3 8.0514 0.1406 219.11 331.80 111. 512.4 8.0649 0.1408 223.43 327.34 102. 512.5 8.0784 0.1411 228.58 322.03 91. 512.6 8.0920 0.1413 235.19 315.27 78. 512.7 8.1055 0.1416 245.09 305.20 58. 512.71 8.1069 0.1416 246.49 303.78 55. 512.72 8.1083 0.1416 248.03 302.22 52. 512.73 8.1096 0.1416 249.77 300.47 49. 512.74 8.1110 0.1417 251.76 298.46 45. 512.75 8.1123 0.14174 254.16 296.04 40. 512.76 8.1137 0.14176 257.23 292.95 34. 512.77 8.1150 0.14179 261.93 288.23 25. 512.777 8.1160 0.14180 275.07 275.07 , (2.5, 3.4, 3.5) (4.5). 2H5OH l, /3 g, / , s, r, / 463.15 577.6761 39.19424 2.4356397 547. 473.15 554.8938 49.283601 2.97220688 505. 483.15 528.4461 62.273371 3.59433734 457. 493.15 496.1959 79.935138 4.31248311 398. 503.15 452.6075 107.465343 5.14004996 317. 513.15 364.2181 180.832631 6.09623388 147. 513.2 363.2354 181.736339 6.10138498 145. 513.3 361.2046 183.608896 6.1116993 141. 513.4 359.0775 185.577035 6.12202981 138. 513.5 356.8419 187.653132 6.13237657 134. 513.6 354.4825 189.852338 6.14273966 130. 513.7 351.9803 192.193513 6.15311912 126. 513.8 349.3113 194.700605 6.16351504 121. 513.9 346.4442 197.404741 6.17392748 116. 514.0 343.3373 200.347572 6.18435652 111. 514.1 339.9324 203.586872 6.19480224 105. 514.2 336.1454 207.206597 6.20526472 99. 514.3 331.8459 211.336597 6.21574406 92. 514.4 326.8138 216.196229 6.22624035 84. 514.5 320.6235 222.210008 6.23675371 74. 514.6 312.2249 230.425511 6.24728427 61. 514.65 306.2182 236.336275 6.25255605 52. 514.66 304.7269 237.807786 6.25361093 50. 514.67 303.0845 239.430192 6.25466598 47. 514.68 301.2458 241.248515 6.25572121 44. 514.69 299.1396 243.334008 6.25677662 41. 514.7 296.6411 245.811211 6.2578322 37. 514.71 293.4951 248.935197 6.25888795 33. 514.72 288.9925 253.414604 6.25994389 26. 514.73 271.19 271.19 6.261 , (2.5, 3.4, 3.5) (4.5). DEE d2Ps/dT l g Cv2 Cs Ps dPs/dT r - -1 K- - -3 - Ma MaK-1 aK K-1 400.00 1,162 0.0232 0,3480 564.30 34.900 2.4120 249.04 -1. 410.00 1,412 0.0268 0,3770 545.84 42.775 2.1390 237.27 -2. 420.00 1,700 0.0307 0,4020 525. 64 52.535 1.8470 221.34 -2. 425.00 1,859 0.0328 0,4130 514.66 58.372 1.7150 211.72 -2. 430.00 2,028 0.0348 0,4240 502.92 65.019 1.5800 200.91 -2. 435.00 2,208 0.0370 0,4360 490.22 72.664 1.4470 188.87 -3. 440.00 2,398 0.0392 0,4510 476.27 81.573 1.3200 175.45 -3. 445.00 2,600 0.0415 0,4720 460.65 92.152 1.2010 160.54 -3. 450.00 2,814 0.0440 0,5060 442.64 105.07 1.0940 143.70 -4. 455.00 3,041 0.0466 0,5640 420.90 121.61 1.0010 124.13 -5. 460.00 3,281 0.0497 0,6750 392.27 144.78 0.9070 99.668 -6. 461.00 3,331 0.0504 0,7100 385.06 150.84 0.8960 93.726 -6. 462.00 3,382 0.0511 0,7510 377.03 157.70 0.8810 87.171 -7. 463.00 3,434 0.0519 0,8020 367.88 165.64 0.8600 79.782 -8. 464.00 3,486 0.0527 0,8660 357.08 175.17 0.8270 71.176 -10. 465.00 3,539 0.0536 0,9550 343.53 187.39 0.7720 60.516 -15. 466.00 3,593 0.0546 1,0160 323.95 205.53 0.6620 45.320 -20. 466.10 3,599 0.0547 1,1210 321.29 208.04 0.6520 43.266 -22. 466.20 3,604 0.0549 1,1450 318.38 210.79 0.6390 41.036 -24. 466.30 3,610 0.0550 1,1720 315.16 213.85 0.6220 38.567 -27. 466.40 3,615 0.0551 1,2040 311.54 217.30 0.6250 35.798 -32. 466.50 3,621 0.0552 1,2420 307.34 221.33 0.6020 32.594 -45. 466.70 3,632 0.0555 1,3640 295.49 232.82 0.4880 23.602 -88. 466.80 3,638 0.0556 1,5250 283.75 244.35 0.3490 14.761 -229. 466.83 3,639 0.0557 1,7310 274.56 253.47 0.2170 7.8830 -1313. 466.836 3,640 0.0557 2,2860 264.00 264.01 0.0000 0.0000 (r, Cv2, Cs), (2.5, 3.4, 3.5) (4.5). H2O Cs, Cv2, T, K r, / / / 640.15 0.011 546.218 -42.201 6. 645.15 3.137e-3 339.481 -76.107 4. 646.15 1.592e-3 263.9 -100.784 3. 646.35 1.282e-3 243.824 -116.845 3. 646.55 9.735e-4 220.531 -142.52 2. 646.75 6.644e-4 192.095 -174.454 2. 646.85 5.099e-4 174.679 -211.523 2. 646.95 3.554e-4 153.554 -256.424 2. 647.00 2.781e-4 140.745 -306.493 1. 647.05 2.009e-4 125.431 -394.629 1. 647.1 1.236e-4 105.709 -484.562 1. 647.11 1.082e-4 100.865 -531.184 1. 647.12 9.271e-5 95.555 -591.498 1. 647.13 7.726e-5 89.641 -673.397 1. 647.14 6.181e-5 82.909 -792.842 1. 647.15 4.635e-5 74.982 -988.722 1. 647.16 3.09e-5 65.096 -1.395e3 0. 647.17 1.545e-5 51.146 -5.115e3 0. 647.18 0 0 - E (r,) . 2 r, /, r, /, r, /, (2.5, (2.5, 3.4, 3.5), (4.5) T,K 2.23, 2.24) (3.2) 515.15 2687.00 1749.52 1358. 525.15 2468.00 1700.1 1322. 535.15 2260.00 1647.28 1283. 545.15 2070.00 1590.42 555.15 1896.00 1528.85 1199. 565.15 1737.00 1461.87 1152. 575.15 1590.00 1388.6 1101. 585.15 1451.00 1307.91 1046. 595.15 1315.00 1218.24 984. 605.15 1180.00 1117.15 914. 615.15 1038.00 1000.44 832. 620.15 961.46 933.96 785. 625.15 879.77 859.91 731. 631.15 769.99 756.83 655. 635.15 685.23 674.99 593. 636.15 661.86 652.15 575. 637.15 637.35 628.09 557. 638.15 611.49 602.6 537. 639.15 584.04 575.42 515. 640.15 554.65 546.22 492. 641.15 522.82 514.5 467. 642.15 487.86 479.57 438. 643.15 448.64 440.33 406. 644.15 403.23 394.9 368. 645.15 347.68 339.48 320. 646.15 271.13 263.9 253. 646.25 261.17 254.19 244. 646.35 250.49 243.82 235. 646.45 238.94 232.67 225. 646.55 226.29 220.53 213. 646.65 212.21 207.15 201. 646.75 196.17 192.1 187. 646.85 177.26 174.68 646.95 153.53 153.55 150. 647 138.48 140.74 138. 647.05 119.37 125.43 123. 647.06 114.75 121.94 120. 647.07 109.73 118.25 116. 647.08 104.23 114.34 113. 647.09 98.08 110.18 109. 647.1 91.05 105.71 104. 647.11 82.75 100.87 100. 647.12 72.34 95.55 94. 647.13 57.52 89.64 89. 647.14 83.63 83. 8. (Cv2,) .

2 Cv2, d2Ps/dT2, Ma/K2, d2Ps/dT2, / , (2.5, Ma/K2, (2.49, Y1, (2.5, 3.4, 3.5), =0.5) (2.49, =0.5) T,K (4.5) 3.4, 3.5) 630.15 0.002273889 0.002285 5.64 8. 635.15 0.002469852 0.002468 4.62 7. 636.15 0.002518291 0.00251 4.409 7. 637.15 0.002571314 0.002554 4.194 6. 638.15 0.002630023 0.002602 3.973 6. 639.15 0.002695963 0.002652 3.747 6. 640.15 0.002771396 0.002706 3.512 6. 641.15 0.002859797 0.002765 3.266 5. 642.15 0.002966883 0.00283 3.006 5. 643.15 0.00310294 0.002903 2.724 5. 644.15 0.003289076 0.002987 2.411 5. 645.15 0.003578791 0.003089 2.045 4. 646.15 0.004177771 0.003229 1.568 4. 646.25 0.004283203 0.003247 1.508 4. 646.35 0.004406259 0.003267 1.445 4. 646.45 0.004552736 0.003288 1.377 4. 646.55 0.00473153 0.003311 1.303 3. 646.65 0.004957156 0.003338 1.222 3. 646.75 0.005255334 0.003368 1.132 3. 646.85 0.005677345 0.003404 1.028 3. 646.95 0.006346014 0.00345 0.902 3. 647 0.006871278 0.00348 0.826 3. 647.05 0.007673107 0.003518 0.736 3. 647.06 0.007890723 0.003527 0.715 3. 647.07 0.008137209 0.003537 0.693 3. 647.08 0.00841961 0.003548 0.67 3. 647.09 0.008747635 0.003559 0.646 3. 647.1 0.00913512 0.003572 0.62 3. 647.11 0.009602608 0.003587 0.591 3. 647.12 0.01018217 0.003603 0.56 3. 647.13 0.010927379 0.003623 0.525 3. 647.14 0.011936247 0.003647 0.486 3. 647.15 0.013413604 0.003677 0.439 3. 647.16 0.015890212 0.00372 0.381 3. 647.17 0.021476801 0.003794 0.299 4. 647.171 0.022508321 0.003805 0.289 4. 647.172 0.02372752 0.003818 0.277 4. 647.173 0.025199064 0.003833 0.265 4. 647.174 0.02702502 0.00385 0.251 4. 647.175 0.029373882 0.00387 0.235 4. 647.176 0.032555674 0.003896 0.218 4. 647.177 0.037218162 0.003922 0.197 4. 647.178 0.045042277 0.003977 0.171 4. 9. (Cs,) .

2 Cs, Cs, Cs, / , / , (2.5, / , (2.49, 3.4, 3.5), (4.5) (2.49, =0.5) =0.13) T,K 640.15 -32.569 -32.394 -34. 642.15 -39.987 -39.719 -39. 643.15 -46.121 -45.797 -45. 644.15 -56.029 -55.649 -55. 645.15 -76.107 -75.706 -75. 646.15 -97.501 -97.154 -99. 646.35 -111.952 -111.681 -116. 646.55 -134.193 -134.075 -142. 646.75 -174.454 -174.69 -174. 646.85 -211.523 -212.143 -212. 646.95 -256.424 -257.554 -257. 647 -306.493 -308.235 -310. 647.05 -349.74 -352.034 -352. 647.06 -368.784 -371.328 -376. 647.07 -390.782 -393.619 -394. 647.08 -416.547 -419.731 -420. 647.09 -447.236 -450.84 -452. 647.1 -500.184 -488.683 -494. 647.11 -531.184 -535.962 -537. 647.12 -591.498 -597.138 -599. 647.13 -673.397 -680.228 -683. 647.14 -792.842 -801.442 -807. 647.15 -988.722 -1.000e3 -1.005e 647.16 -1.395e3 -1.413e3 -1.419e 647.17 -1.839e3 -1.864e 647.171 -1.977e3 -2.004e 647.172 -2.145e3 -2.174e 647.173 -2.355e3 -2.388e 647.174 -2.626e3 -2.664e 647.175 -2.995e3 -3.038e 647.176 -3.533e3 -3.585e 647.177 -4.416e3 -4.482e

Pages:     | 1 |   ...   | 3 | 4 ||
 
 >>  ()





 
<<     |    
2013 www.libed.ru - -

, .
, , , , 1-2 .