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, . 31 , 20%.

(2, 2, 2) (2, 2) . , 1H, 13C 31-, . . 2 . 3.

, 1H (2, 2) 2, P-CH2CH, P-CH2CH NCH2 .

1, 13 - 1, 13 (2, 2, 2) . , 13 C3-C, C-CP C-P .

, 3- - P,N()- , : , , , .

1.

3- , . , 3- , , % ,% , 60- 2 1 HP(O)Ph2 8 100 , 75- 2 1 HP(O)Ph2 8 100 , 60- 2 1 HP(S)(CH2CH2Ph)2 8 100 , 65- 2 1 HP(S)(CH2CH2Ph)2 8 100 , 65- 2 1 HP(S)(CH2CH2Ph)2 5 100 , 75- 2 1 HP(O)(Ph)2 10 100 , 75- 2 1 HP(S)(CH2CH2Ph)2 20 70 . . .

2.

(2-2) ,, .., J, , . 1 13 H C P 1 2 3 4 : 23.169 (C11), 40.15 (C12, 1JPC = 71.6), 40.84 (C6), : 3.01-3,07 O 103.06 (C4), 126. (4H, C11, 12H), 5.34 P (C9), 126.87 (C5), (2H, C6H), 6.12 (1H, 127.32 (C10), 128.19 CDCl3:

N C4H, 3J4,5 = 1.7), 7.14 N (C8), 128.72 129.24 42. (1H, C5H, 3J4,5 = 1.7), 2 (C15, 3JPC = 10.62), 7 7.147.43 (15H, C14 130.98 131.14 (C13, 16, 8- H) 10 JPC = 10.1), 133. [2-(1--3 (14), 134.98 (16), )] 158.16 (3) CDCl3: 28.48 (C10), 10 9 29.91 (C8, 1JPC = CDCl3: 1.99-2.06 S 49.15), 31,53 (C7), 8 P (4H, C10-H), 2.09-2. 32.42 (C9, 1JPC = (2H, C7-H), 2.82 48.1), 35.68 (C6), :

N 2.86 (6 H, C8,9H), Cl N 103.21 (C4), 126.31 48. 3.54 (3H, N-Me), (C14), 127.37 (5), Me 5.93 (1H, C4), 2 128.08 (C12), 128. [2-(1--5- 6.977.15 (10H, C11 (C13), 140.59 (C11, -3- H) )] JPC = 13.9), 151, (C3, 3JPC = 13.9) CDCl3: 11.09 (C8), CDCl3: 0.71 (3H, 23.03 (C7), 28, 8 (C12), 29.48 (C9), C H, J6,8 = 7.1), 1.65 11 1.76 (2H, C7H), 2.05- 29.89 (C10, 1JPC = S 10 P 2.10 (4H, C H), 49.5), 32.80 (C11, 1JPC 2.12-2.19 (2H, C9H), = 48.4), 50.24 (C6), DCl3:

N 2.86-2.93 (6H, 103.21 (C4), 126. Cl 48. N 8 10, H), 3.80 (3H, 16 2 C (C ), 127.99 ( ), Me 7 C6H, 4J6,8 = 7.1), 5.98 128.38 (C14), 128. [2-(1--5 (C15), 140.35 (C13, (1H, C4), 7.047.24 -3- (10H, C14-15H) JPC = 14.3), 150, )] (C3, 3JPC = 13.9) CDCl3: 1.32 (3H, C H, 3J6,7 = 7.2), 3.34 CDCl3: 12.37 (C7), (3H, C14H, 3J8,14 = 6.9), 15.20 (C14), 32. Me O 10 3.00 (1H, C -H, (C8), 41.41 (C9, 1JPC = * JHH = 14.8, 2JHH = 70.1), 44.19 (C6), 9P 4 14.9), 3.27 (1H, 102.91 (C4), 125. :

5 9 2 C H, JHH = 14.9, JHH (C5), 128.16 129. N Cl 33. N = 14.8), 3.61 3.92 (C12, 3JPC = 11.4), 6 8 (1H, C H, J8,14 = 6.9), 130.54 130.96 (C10, 2 Me - 3.77 3,92 (2H, C6H, JPC = 9.2), 131. [1--2-(1--5- J6,8 = 7,2), 6.40 (1H, (11), 132.30 (13), -3- 157.71(3) C4), 7.257.75 (10H, )] 11- C H) CDCl3: 10.38 (C8), CDCl3: 0.76 (3H, C - 22.67 (C7), 23. H, 4J6,8 = 7.4), 1.31 (C17), 30,70 (C12), 11 Me S (3H, C17H, 3J9,17 = 7.5), 31.07 (C11, 1JPC = * 10 P 1.56-1.62 (6H, 57.6), 31.57 (C9, 2JPC 10, H), 1.94-2.02 = 48.05), 32.46 (C10, C :

N (4H, C12H), 3.36 (1H, Cl JPC = 48.42), 50, N 47. C9H, 3J9,17 = 7.46), 3.85 (C6), 101.90 (C4), Me 7 (2 H, C6H, 3J6,8 = 125.85 (C16), 127. 2 [1--2-(1- 7.43), 6.08 (1H, (5), 127.81 128. -5--3 (C15), 128.07 (C14, C4H), 7.007.30 )] (10H, C14-16H)) JPC = 17.3), 140. (C13), 155,01 (C3) (-3 ) - (2-2 ) , % , % .

C H Cl N P S C H Cl N P S 74.8 5.9 7.1 8.3 3.7 74.8 5.7 7.3 8.1 4. 2 - C24H22ON2P 6 4 1 2 7 0 0 0 0 63.7 6.6 8.6 6.1 7.0 7.8 C22H26ClN2P 63.3 6.2 8.5 6.7 7.4 7. 2 3 8 1 5 3 0 S 8 9 0 2 3 64.1 6.8 7.5 6.8 6.6 7.9 C24H30ClN2P 64.7 6.8 7.9 6.3 6.9 7. 2 6 6 3 4 3 8 S 8 0 7 0 6 2022OClN 64.8 5.9 9.4 7.3 8.1 4.3 5.9 9.5 7.5 8.3 4. 2 64. 2 2 2 4 2 8 P 0 0 0 0 65.3 7.1 7.8 6.0 6.4 7.2 C25H32ClN2P 65.4 7.0 7.7 6.1 6.7 6. 2 2 5 2 5 1 5 S 2 3 2 0 5 Bruker IFS-25.

1, 13, 15N, 31P Bruker DPX-400 ( 400.13, 101.61, 40.56, 161.98 ), (1, 13), 3NO2 (15N) 85%- 34 (31). 0.01 0.02 ..

. 0.1 .

DRT-240 ( 240-320 ) 240 .

[2-(1--3-)] (2). 0.21 (0.001 ) 0.18 (0.0012 ) 1--3- (1) 5 , 60-65 8 . . , , 0.34 ( 73%) (2) - .

75-80 2-3 % (2) 78%.

[2-(1--5--3-)] (2). (1) (). .

[2-(1--5--3-)] (2). (1) (). .

[1--2-(1--5--3-)] (2). (1) (). .

[1--2-(1--5--3-)]- (2).

(1) (). .

1. Albrecht C., Gauthier S., Wolf J., Scopelliti R., Severin K. Microwaveassisted organometallic syntheses: formation of dinuclear [(arene)Ru(Cl)3RuCl(LL)] complexes (LL: chelate ligands with P, N, or Sdonor atoms) by displacement of arene ligands // Eur. J. Inorg. Chem. 2009. N 8. P. 10031010.

2. FernandezPerez H., Etayo P., Panossian, A., VidalFerran A. Phosphinephosphinite and phos phinephosphite ligands:preparation and applications in asymmetric catalysis // Chem. Rev. 2011.

Vol. 111. P. 21192176.

3. Trofimov B. A., Malysheva S. F., Sukhov B. G., Belogorlova N. A., Schmidt E. Y., Sobenina L.

N., Kuimov V. A., Gusarova N. K. Addition of secondary phosphines to Nvinylpyrroles // Tetra hedron. 2003. Vol. 44, N. 13. P. 26292632.

4. Trofimov B. A., Gusarova N. K., Sukhov B. G., Malysheva S. F., Tarasova O. A., Belogorlova N. A., Maximova M. A., Tunik S. P. Atomeconomic, solventfree, high yield synthesis of 2 (pyrrol1yl)propyldiorganylphosphines // Synthesis. 2005. N. 6. P. 965970.

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, - (, 2012 .)

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